Conversion of methane and carbon dioxide using catalytic membranes

New effective method for syngas production

Alexey Fedotov - Collection Omn.univ.europ.

72 pages, parution le 10/05/2011

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Résumé

This study reports the development of a new process to convert methane and carbon dioxide into syngas from non-oil resources. The process uses membrane catalytic systems (MCS) that support heterogeneous catalytic reactions in gaseous phase in membrane channels. An active surface of the catalysts formed inside the micro- channels is low in term of area, but it is characterized by a high value of the catalyst surface/volume ratio, which induces a high efficiency of heterogeneous catalysis. Such MCS, having 10 8 pores per cm2 of surface, can be considered as a set of nano reactors. MCS are formed from alkoxy derivatives and precursor metal complex containing between 0.008 and 0.055% by weight of nano- components mono-and bimetallic active distributed evenly in the channels. For systems La-Ce/Ni-Al and Pd-Mn/Ni-Al, productivities of 10500 and 7500 l/h dm3 were respectively obtained at 650°C with a composition of syngas H2/ ranging from 0.63 to 1.25 and a conversion rate of 50% with a CH4/ 2 (1/1) feed. Thus MCS is an order of magnitude more efficient than a fixed bed reactor of the same catalyst. A catalytic synergy has been demonstrated for the system Pd-Mn.

Caractéristiques techniques

	PAPIER
Éditeur(s)	Editions universitaires européennes
Auteur(s)	Alexey Fedotov
Collection	Omn.univ.europ.
Parution	10/05/2011
Nb. de pages	72
Format	15 x 22
Couverture	Broché
Poids	120g
EAN13	9786131574863